Enhanced and tunable photoluminescence of polyphenylenevinylenes confined in nanocomposite films
نویسندگان
چکیده
Conformation of macromolecules and interchain interactions determine spectral properties of conjugated polymers (CP). An achievement of spatial confinement of isolated chains is one of the routes to use this feature of CP for their purposeful usage. In the present work, CP/O300 nanocomposites based on CP - poly(p-phenylenevinylene) and poly(2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene) - and silica nanoparticles (O300) are prepared. In comparison with many previously known hybrid nanomaterials synthesized with the similar purpose, CP/O300 nanocomposites are characterized by the essentially enhanced and tunable photoluminescence. The greatest change of color coordinates is observed for poly(p-phenylenevinylene)-based nanocomposites due to specific preparation method and interaction with the inorganic component. The main emission from CP in the CP/O300 nanocomposites is owing to 0-0 transitions, while 0-1 transitions, associated with aggregate states of the CP chains, are suppressed.
منابع مشابه
Preparation and Characterization (Mechanical and Water Absorption Properties) of CMC/PVA/Clay Nanocomposite Films
The aim of this study was to produce Carboxy Methyl Cellulose (CMC) and Poly Vinyl Alcohol (PVA) films and to enhance their properties by reinforcing them with nanoclay particles. Thus, nanocomposite films were prepared with blending of CMC and PVA, as a matrix and several filler loadings of nanoclay particles. The various formulations of nanocomposite films obtained with casting m...
متن کاملControllable photoluminescence enhancement of CdTe/CdS quantum dots thin films incorporation with Au nanoparticles
Au nanoparticles (Au NPs)/CdTe/CdS QDs nanocomposite films were fabricated by deposition of Au NPs and layer-by-layer self-assembly of colloidal CdTe/CdS QDs. Photoluminescence (PL) spectra showed that Au NPs incorporation resulted in an increase of PL intensity about 16-fold compared with that of the samples without Au NPs. PL enhancement of Au NPs/CdTe/CdS QDs nanocomposite films can be contr...
متن کاملEffect of Fe3+–MMT on thermal degradation and mechanical behavior of PVP/Amylose nanocomposite films
Novel nanocomposite films based on amylose (AM) and Fe3+-montmorillonite (Fe3+–MMT) in the matrix of poly (vinyl pyrrolidone) (PVP) were fabricated by using a solution casting method. The X-Ray diffractional analysis indicated that an ion-exchange process occurred between Fe3+–MMT and PVP. Thermogravimetrical analysis (TGA), differential termogravivetrical analy...
متن کاملRobust multilayer thin films containing cationic thiol-functionalized gold nanorods for tunable plasmonic properties.
Gold nanorods have great potential in a variety of applications because of their unique physical properties. In this article, we present the layer-by-layer (LbL) assembly of thin films containing positively charged gold nanorods that are covalently functionalized by cationic thiol molecules. The cationic gold nanorods are uniformly distributed in ultrathin nanocomposite LbL thin films. We studi...
متن کامل